An Old Reaction Revisited
June 30, 2015

Chemoselective Reductive Amination of Carbonyl Compounds for the Synthesis of Tertiary Amines Using SnCl2·2H2O/PMHS/MeOH A new protocol for a reductive amination…

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Not So Easy
June 23, 2015

Synthesis of Heteroaryl Sulfonamides from Organozinc Reagents and 2,4,6-Trichlorophenyl Chlorosulfate Access to sulfonated heterocycles using zincates and the reagent TCPC. It…

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New CO-nditions
June 10, 2015

Aminocarbonylation of Aryl Tosylates to Carboxamides Generation of aromatic amides using CO, amines and aryl tosylates as coupling substrates. This is…

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June 8, 2015

Oxalyl Chloride as a Practical Carbon Monoxide Source for Carbonylation Reactions A new way to get a balloon filled with CO…

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Ipso Facto
June 1, 2015

Ipso-Borylation of Aryl Ethers via Ni-Catalyzed C–OMe Cleavage The OMe moiety used as entry point for the borylation of aryl and…

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Impressive, Most Impressive
May 27, 2015

Practical olefin hydroamination with nitroarenes A new, powerful method to generate quaternary amines without using expensive catalysts. Baran has done it…

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May 21, 2015

In Situ Generation of Difluoromethyl Diazomethane for [3+2] Cycloadditions with Alkynes Safe preparation of an elusive reagent, difluoromethyl diazomethane, and its…

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Working on the Edge
May 19, 2015

Metal-Free, Regio- and Stereoselective Synthesis of Linear (E)?Allylic Compounds Using C, N, O, and S Nucleophiles Using terminal alkenes to prepare…

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Suzuki on the Rocks
May 14, 2015

Palladium-Catalyzed, Ligand-Free Suzuki Reaction in Water Using Aryl Fluorosulfates Not only we can couple the most exotic moieties, we can do…

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Catalysis for Amides
May 4, 2015

Catalytic Chemical Amide Synthesis at Room Temperature: One More Step Toward Peptide Synthesis An uncommon use of a boronic acid: as…

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