Couplings

Activated
Maio 25, 2016

A general alkyl-alkyl cross-coupling enabled by redox-active esters and alkylzinc reagents Activated esters of alkylic acids as building blocks for the…

Ler máis
(Un)touchable
Xaneiro 25, 2016

Ni/Cu-Catalyzed Defluoroborylation of Fluoroarenes for Diverse C–F Bond Functionalizations Using a mixed catalytic system to promote the transformation of aromatic fluorides…

Ler máis
Multimetals for Biaryls
Outubro 23, 2015

Multimetallic catalysed cross-coupling of aryl bromides with aryl triflates A catalytic system using two metals allows the synthesis of biaryl products…

Ler máis
Bubbles
Xuño 8, 2015

Oxalyl Chloride as a Practical Carbon Monoxide Source for Carbonylation Reactions A new way to get a balloon filled with CO…

Ler máis
Tosylates to the Rescue
Marzo 16, 2015

Engaging Nonaromatic, Heterocyclic Tosylates in Reductive Cross-Coupling with Aryl and Heteroaryl Bromides Reductive coupling of common aliphatic heterocycles (piperidines, pyrrolidines, pyranes…

Ler máis
And I Mean Everything
Marzo 12, 2015

Palladium-Catalyzed Coupling of Azoles or Thiazoles with Aryl Thioethers via C–H/C–S Activation Coupling of azoles and thiazoles with aryl thioeters when…

Ler máis
Sometimes It Happens
Marzo 5, 2015

Nickel-Catalyzed Decarboxylative Cross-Coupling of Perfluorobenzoates with Aryl Halides and Sulfonates Conditions to carry out a Suzuki-like coupling with perfluorinated benzoates. I…

Ler máis
Earth-Abundant Catalyst
Febreiro 18, 2015

Silylation of C–H bonds in aromatic heterocycles by an Earth-abundant metal catalyst C-H activation using a catalyst that is not based…

Ler máis
Not a Poison Anymore?
Febreiro 10, 2015

Synthesis of diaryl thioethers from aryl halides and potassium thiocyanate A method for the preparation of thioethers using a Palladium catalyst…

Ler máis
Drunken Reactions
Xaneiro 28, 2015

Functionalized olefin cross-coupling to construct carbon-carbon bonds A new method for the generation of quaternary centers using Fe catalysis. Some years…

Ler máis