Nickel

Activated
May 25, 2016

A general alkyl-alkyl cross-coupling enabled by redox-active esters and alkylzinc reagents Activated esters of alkylic acids as building blocks for the…

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(Un)touchable
January 25, 2016

Ni/Cu-Catalyzed Defluoroborylation of Fluoroarenes for Diverse C–F Bond Functionalizations Using a mixed catalytic system to promote the transformation of aromatic fluorides…

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Multimetals for Biaryls
October 23, 2015

Multimetallic catalysed cross-coupling of aryl bromides with aryl triflates A catalytic system using two metals allows the synthesis of biaryl products…

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Ipso Facto
June 1, 2015

Ipso-Borylation of Aryl Ethers via Ni-Catalyzed C–OMe Cleavage The OMe moiety used as entry point for the borylation of aryl and…

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Tosylates to the Rescue
March 16, 2015

Engaging Nonaromatic, Heterocyclic Tosylates in Reductive Cross-Coupling with Aryl and Heteroaryl Bromides Reductive coupling of common aliphatic heterocycles (piperidines, pyrrolidines, pyranes…

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Sometimes It Happens
March 5, 2015

Nickel-Catalyzed Decarboxylative Cross-Coupling of Perfluorobenzoates with Aryl Halides and Sulfonates Conditions to carry out a Suzuki-like coupling with perfluorinated benzoates. I…

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…And Keeps Going
December 1, 2011

Ni(COD)2/PCy3 Catalyzed Cross-Coupling of Aryl and Heteroaryl Neopentylglycolboronates with Aryl and Heteroaryl Mesylates and Sulfamates in THF at Room Temperature Coupling…

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Anything goes…
December 1, 2011

Nickel-Catalyzed Suzuki–Miyaura Reaction of Aryl Fluorides Coupling of fluoroaromatics with boronates using a Nickel catalyst. It is official: We can couple…

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What you Missed Last Month
December 1, 2011

What can we say? CPhI is really important and we had some very important activities going on, such as preparing the…

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C-O No More
November 1, 2011

Ni-Catalyzed Reduction of Inert C-O Bonds: A New Strategy for Using Aryl Ethers as Easily Removable Directing Groups Cleavage of the…

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